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April 8, 2022

Halogenated FRs in China recycled plastics

Based on measurements in plastics samples, tonnages of halogenated FRs in recycled plastics in China were estimated. Total levels of twelve halogenated flame retardants (HFRs)* were measured in 23 samples of recycled plastics, manufactured in five Chinese provinces. Mean total HFR concentrations were approx. 4 – 60 µg/kg for different recycled polymers tested**.

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PIN compounds to recycle polyurethanes

Phosphorus, nitrogen and inorganics used in polyurethane chemical recycling produce PIN flame retardant recycled PUR. Glycolysis is the most widespread route for chemical recycling of polyurethanes (PUR). Glycols or glycerol (which can be bio-derived), with catalysts, are used as depolymerising agents (usually at around 180 to 240°C).

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PIN FR recycled denim fire blocks

Denim cotton fabric can be recycled using PIN flame retardants to produce composite boards for fire compartmentation. The world produces some 150 million t/y of textile waste.

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UV cured PIN FR coating

Texas A&M scientists propose phosphorus-based one-dip UV cured fire protective coatings for wood and other materials. The new coating presented at the ACS (American Chemical Society) conference uses an aqueous solution of hydroxyethyl methacrylate phosphate (HMP) monomer, polyethylenimine (PEI) polymer and a the photoinitiator TPO.

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Polyphosphonate obtains GreenScreen®

pinfa member FRX Polymers’ polymeric phosphorus PIN FR GreenScreen 3 Benchmark recognises safety and non-toxicity. GreenScreen is a leading ESG (Environmental, Social, and Governance criteria), referenced by mainstream labelling organisations, for example the TCO label (see above).

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PIN FR Fabric-over-Foam EMI gaskets

Laird (Dupont group) offers non-halogenated flame retardant EMI (electromagnetic interference) gaskets. With roots back to 1824, and after acquisitions including Emerson & Cuming, BMI, Steward, and Thermagon, Laird Performance Materials is today part of Dupont and specialises in materials for protection of electronic devices from harmful heat and disruptive electromagnetic interference

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Silicon phosphorus nitrogen FR for PLA

A silicon polyphosphoramide was synthesised and tested as a PIN flame retardant for bio-based polylactide plastic.

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Iron alginate bio-based PIN FR for epoxy

Iron alginate at 8% w/w in epoxy resin halved both peak heat release rate and smoke release rate in epoxy. Iron alginate was produced by aqueous reaction of sodium alginate, which can be extracted from marine plants, with the ferric salts, then dried, pulverised and mixed into epoxy resin during curing.

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March 7, 2022

EU consultation on RoHS

To 14th March 2022. Questions whether RoHS Directive should be maintained, updated, tightened, repealed or replaced.

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New York Br-FR ban in TVs amended

The NY ban on brominated FRs in TV/display stands and casings now requires notification of any organohalogen FRs.

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Consultation on supply chain transparency

To 25th March, Canada, consultation on information and labelling on chemicals in products, including FRs in furniture

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EU EcoDesign sells TVs in the Americas

‘Best Buy’ announces EU TV EcoDesign criteria for its leading TVs, so excluding halogenated FRs from enclosures and stand. The company is one of the world’s biggest electronics retailers with nearly US$50 billion turnover and nearly 1 200 stores worldwide.

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UK businesses fail on fire safety

Survey by equipment & servicing company JLA says UK companies do not ensure fire safety for sites, staff and visitors.

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WWF on chemical recycling of plastics

NGO says top priorities are to reduce and reuse, and chemical recycling must show verifiable, positive carbon footprint.

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pinfa Annual Report 2021

An active year for pinfa in Europe & worldwide: five new members, strategy and advocacy, new communications tools.

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Recycling and perspectives for FRs

pinfa has launched an analysis of how recycling regulation and technologies will offer opportunities for PIN flame retardants.

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pinfa roadmap for Chemicals Sustainability

pinfa has outlined a Chemicals Strategy for Sustainability roadmap for FRs to address Green Deal opportunities. The EU Chemicals Strategy for Sustainability, part of the Green Deal, was published in October 2020 and foresees far-reaching developments in chemicals regulation and policies in Europe (summary pinfa Newsletter n°119).

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1 000 London buildings are fire-unsafe

London Fire Brigade says 1 149 buildings in London need a 24-hour “waking watch” because of severe fire safety defects. These “waking watches” were put into place in fire-unsafe buildings in London following the Grenfell Tower fire, in which 72 people died.

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Numerical modelling of Grenfell fire – bis

Modelling study, funded by Kingspan, concludes tenability inside Grenfell flats was independent of insulating material. Kingspan is the manufacturer of one of the insulation cladding products which burnt in the Grenfell Tower fire.

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Fire retardant coatings for wood and timber

The European Coatings webforum showed how PIN FRs enable safe use in buildings of the renewable material, wood. The webinar, hosted by Katrin Vogt, European Coatings Journal,  brought together nearly...

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Budenheim

Sebastian Moschel, Budenheim (pinfa member), underlined that use of wood in construction is growing at 3.2% per year, and is desirable both for environmental reasons (carbon sequestration) and for aes...

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Sika Deutschland

Markus Wöhr, Sika Deutschland (soon to be a member of the Sherwin Williams group), explained that FR intumescent coatings combine a blowing agent, carbon source, catalyst, and a binder, and so generate a protective carbon char foam in case of fire.

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Demand for PIN FRs expected to grow

New market studies predict ongoing growth in global demand for flame retardants, especially PIN FRs, driven by fire safety, increased used of polymers and other flammable materials, and environmental and recycling requirements.

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PIN FR performance PPA for EVs and E&E

Solvay’s partially bio-based long-chain PPA achieves UL94 V-0 (at 0.4 mm) with processability, strength and stability. The non-halogenated flame retardant polyphthalamide formulations offer processing advantages of high glass transition temperature and melting point (Tg 135°C, Tm 315°C) adapted to non-blistering reflow soldered surface mount devices (SMD) and parts in cooling systems for power electronics or fluid connectors, and to production of miniaturised components

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