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September 12, 2022

pinfa GA addresses the Green Deal

pinfa members working together on opportunities offered by for PIN flame retardants by the EU Green Deal.

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New chairman of pinfa-NA: Carolyn Pressley

Pinfa North America has elected Carolyn Pressley, Budenheim USA, as Chairman for 2-year term, from 1st July 2022.

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Safety by Durability

pinfa infographics explain why chemical stability of PIN FRs is key to Green Deal product durability objectives.

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Road to Flame Retardant Commercialisation

pinfa-NA member, Dr. Anteneh Worku (FR Adviser LLC) presents challenges of FR design and production. pinfa North America (pinfa-NA) was a sponsor of the ACS Fire and Polymers 2022 workshop

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Possible restriction of halogen FRs in E&E

State proposes to restrict all halogenated flame retardants (HFFRs) in E&E enclosures and stands. The proposal from the Washington State Ecology Department takes forward the SAFER “priority products” process (law RCW 70.365, see pinfa Newsletter n°108).

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Cancer recognised as firefighter health risk

The WHO’s IARC has classified cancer as an exposure risk for firefighters. At an expert meeting 1st July 2022, IARC classified occupational exposure as a firefighter as carcinogenic to humans (Group 1)

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EU reports record wildfires in 2022

The EU’s Copernicus (CAMS) data show record wildfire activity in South West Europe. Germany, Eastern Europe and Baltic States are also affected.

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Whirlpool sued 1.3 M£ for tumble-dryer fire

Legal action by a London borough adds to payments already made to 37 residents and recall of half a million driers. In August 2016, a fire started in a flat on Heathstan Road, Shepherds Bush, caused by tumble drier (according to the London Fire Brigade investigation).

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Miami plane crash landing fire

126 people escaped with no major injuries when RED Air MD-80 crash landed and caught fire at Miami International Airport 21st June 2022.

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Court orders 8 M£ for combustible cladding

UK court condemns contractor to pay replacement costs of combustible polystyrene insulation cladding and fire barriers.

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Do flame retardants impact smoke toxicity?

Furnished room fire tests conclude that flame retardants do not increase smoke toxicity. The room tests are described in Blais 2020 (see pinfa Newsletter n°104).

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PlasticsEurope calls for faster recycling

The EU plastics industry federation reports on benefits and opportunities of recycling and calls for incentives. The “ReShaping Plastics” report (SYSTEMIQ for PlasticsEurope) says current industry and policy actions could more than double plastics recycling from 14% today to 33% in 2030, reducing greenhouse emissions and waste.

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“Circularizing the Electronics Industry”

z2data Webinar with Design Chain Associates says circularity drives to sustainable chemicals, and EU Green Deal policies will make this happen.

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Recycling of PIN FR from PC/ABS

Solvent is shown to dissolve the phosphorus FR BDP from PC/ABS, enabling recovery of the PIN FR for recycling.

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Mechanical recycling of PIN FR epoxy

The PIN FR DOPO is shown to achieve fire and mechanical performance, transparency and recyclability in epoxy. The commercial phosphorus PIN FR 9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide (DOPO) was pre-reacted into DGEBA epoxy before curing.

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Polyphosphonate FR for quality cars

pinfa member, FRX Innovations (FRW Polymers), has started supplying PIN FR for use in interiors by a leading German car manufacturer.

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NGOs campaign on FRs in children’s car seats

US environmental health NGO “The Ecology Center” (Michigan) has published analysis of 600 components (fabric, foam, structural plastics) from 25 car seats (3 from the EU, 22 from the USA).

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Substitute brominated FR shows thyroid toxicity

BTBPE = 1, 2-bis (2,4, 6-tribromophenoxy) ethane has been used to substitute the now-banned brominated flame retardant Octa-BDE (listed as POP in 2009).

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Low risk from FRs in dust at vehicle and electronics dismantling sites

Some fifty different FRs were analysed in settled dust from a total of 18 informal e-waste and end-of-life vehicle processing workshops  in Vietnam.

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Studies on phosphorus flame retardants

Infant exposure to organo-phosphorus FRs (OPFRs). A study of 259 children aged 3.5 years and 388 mothers in France (ELFE cohort) found nine OPFRs (out of 15 analysed) in at least one fifth of hair samples.

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July 8, 2022

ECOFRAM 2022

This pinfa Newsletter summarises ECOFRAM 2022, the third International Conference on Eco-Friendly Flame Retardant Additives and Materials, Alès, France, 17-18 May 2022 (postponed from 2020 because of Covid).

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Industry actions for sustainable fire safety

Christian Battenberg, Clariant, presented the company’s objectives of climate impact reduction, the product portfolio sustainability assessment system and the Clariant “Ecotain” label for best-in-class products (pinfa Newsletter n°79). Clariant has fixed the objective to reduce greenhouse gas emissions by 40% for scope 1+2 and by 14% for scope 3 (link) between 2019 to 2030.

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New applications for PIN flame retardants

Sabyasachi Gaan, EMPA Switzerland, presented testing of PIN FRs in reactive extrusion of polyamide. An oligomeric phosphorus PIN flame retardant was embedded in polyamide, by reaction of a phosphorylated vinyl monomer (DVPPO) with the cyclic amine (piperazine) in extrusion of polyamide polymer to fibres, so embedding the resulting phosphorus-nitrogen macromolecules in the polyamide matrix.

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Environment and safety

Jérémie Pourchez, Mines Alès France, presented analysis of nano-particles in fly ash (from offgas filters) and bottom ash, both from laboratory incineration of ethylene vinyl acetate polymer containing nano-minerals: silica, alumina, boehmite, zinc, titanium.

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